Super Unleaded is a higher octane fuel, typically 98 against normal unleadeds 95. To make the most of this your ecu needs to be mapped for that fuel. You will see that some performance cars MUST be run on super because their engines are highly tuned and mapped for it.
Whether it makes any difference in a normal car will be down to how advanced the ecu is, if the ecu is sophisticated enough to adjust the mapping for different grades of fuel then it will give better performance, if not then you might as well stuff a couple of £10 pound notes in the tank.
Super unleaded is typically 10p a litre more expensive and rare as hens teeth in NI and therefore it would seem like madness to run it in a std car. Hell I don't even use it in the Caterham even though I had the opportunity to have the car mapped specifically for super green.
Just use ordinary......or perhaps you don't think fuel is expensive enough already.
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